Date | 05 Aug 2024 |
Time | 5:30 pm - 6:30 pm (HKT) |
Venue | Lecture Theatre P3, Chong Yuet Ming Physics Building |
Speaker | Prof. Henri-Pierre Jacquot de Rouville |
Institution | Institut de Chimie de Strasbourg (UMR CNRS 7177), Université de Strasbourg |
![Self Photos / Files - Prof. HPJ de Rouville seminar poster](/upload/events_seminars_conferences/311/self/66a05bf869376.jpg)
Université de Strasbourg
Equilibria involving multiple interacting life components gave rise to complex assemblies (double helix of DNA, G-quadruplex secondary structures). In addition, living organisms are endowed with numerous remarkable and complex functions (transmission of information, chemical transformations, transport, regulation) mediated by physical and chemical stimuli. In consequence, understanding and mimicking these functions using switchable artificial supramolecular systems is of paramount importance and still remains a current challenge.
We recently reported bis-acridinium supramolecular receptors able to bind guest molecules (Figure 1).1 Surprisingly, acridinium-based receptors are scarcely exploited in supramolecular chemistry despite their multi-responsive properties. Indeed, they respond to chemical and redox signals by reversibly modifying their shape, their chemical and optical properties.2 This class of receptors exhibits i) self-complementary behaviors leading to the formation of entwined dimers,1a ii) narcissistic self-sorting,1b iii) p-donor/p-acceptor host-guest behaviors and were also studied as selective phase transfer agents in perfluorocarbons.3 In addition, the multi-switching properties of these receptors were investigated to alter their recognition events with guests. An increasing complexity has been achieved by the introduction of acridinium units in mechanically interlocked molecules.4 The dual-readout of the mechanical response of a [2]rotaxane structure was thus probed. Finally, the combination of the acridinium unit to another multi-responsive unit, namely porphyrin core, led to complex supramolecular systems exhibiting more than eight different states.5